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LECTURE 9

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STRUCTURE OF COMPLEXES: STRUCTURE OF COMPLEXES: Central Metal Ion: It is an acceptor atom containing vacant orbitals to which a fixed number of ligands are attached via co-ordinate bonds in definite geometrical arrangement. The molecules or ions coordinating to the metal are the ligands. They are usually anions or polar molecules.

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Classification of complex compounds: By the charge of the complex ion

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Nomenclature of Coordination Compounds The basic protocol in coordination nomenclature is to name the ligands attached to the metal as prefixes before the metal name. Some common ligands and their names are listed above.

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Nomenclature of Coordination Compounds As is the case with ionic compounds, the name of the cation appears first; the anion is named last. Ligands are listed alphabetically before the metal. Prefixes denoting the number of a particular ligand are ignored when alphabetizing.

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Nomenclature of Coordination Compounds The names of anionic ligands end in “o”; the endings of the names of neutral ligands are not changed. Prefixes tell the number of a type of ligand in the complex. If the name of the ligand itself has such a prefix, alternatives like bis-, tris-, etc., are used.